Sensing mechanism of a fluorescent probe for thiophenols: Invalidity of excited-state intramolecular proton transfer mechanism
Xiaofei Sun, Chuipeng Kong, Hong‐Xing Zhang
Topics & Concepts
FluorescenceIntramolecular forceDensity functional theoryPhotochemistryExcited stateChemistryEnolMolecular orbitalTime-dependent density functional theoryQuenching (fluorescence)ProtonMoleculeComputational chemistryAtomic physicsStereochemistryCatalysisBiochemistryPhysicsOrganic chemistryQuantum mechanicsPhotochemistry and Electron Transfer StudiesFree Radicals and AntioxidantsPorphyrin and Phthalocyanine Chemistry