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General and selective synthesis of primary amines using Ni-based homogeneous catalysts

Kathiravan Murugesan, Zhihong Wei, Vishwas G. Chandrashekhar, Haijun Jiao, Matthias Beller, Rajenahally V. Jagadeesh

2020Chemical Science45 citationsDOIOpen Access PDF

Abstract

A Ni-triphos based homogeneous catalyst enabled the synthesis of all kinds of primary amines by reductive amination of carbonyl compounds with ammonia and hydrogenation of nitroarenes.

Topics & Concepts

TriphosPrimary (astronomy)HomogeneousCatalysisReductive aminationAminationAmmoniaChemistryHomogeneous catalysisOrganic chemistryCombinatorial chemistryAmmonia productionMathematicsPhysicsAstronomyCombinatoricsNanomaterials for catalytic reactionsAsymmetric Hydrogenation and CatalysisAmmonia Synthesis and Nitrogen Reduction
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