Litcius/Paper detail

The visible-light-induced acylation/cyclization of alkynoates with acyl oximes for the construction of 3-acylcoumarins

Quan Zhou, Fang‐Ting Xiong, Pu Chen, Biquan Xiong, Kewen Tang, Yu Liu

2021Organic & Biomolecular Chemistry17 citationsDOI

Abstract

A nitrogen-centered radical-mediated carbon–carbon bond cleavage strategy for the construction of 3-acylcoumarins via the visible-light-induced cascade acylation/cyclization of alkynoates with acyl oxime compounds is reported.

Topics & Concepts

AcylationChemistryOrganic chemistryCatalysisRadical Photochemical ReactionsSulfur-Based Synthesis TechniquesCatalytic C–H Functionalization Methods