Sensitivity of the glass transition and melting in a metal–organic framework to ligand chemistry
Rasmus S. K. Madsen, Sounak Sarkar, Bo B. Iversen, Yuanzheng Yue
Abstract
The effect of substituting linkers with electron-donating moieties for part of the conventional ones on the melting and glass transition behaviours of ZIF-62 was investigated by calorimetry and X-ray diffraction.
Topics & Concepts
Glass transitionTransition metalChemistryLigand (biochemistry)CalorimetryBenzimidazoleCrystallographyDiffractionDifferential scanning calorimetryOrganic chemistryPolymerThermodynamicsCatalysisReceptorPhysicsBiochemistryOpticsMetal-Organic Frameworks: Synthesis and ApplicationsCrystallography and molecular interactionsMagnetism in coordination complexes