Unsymmetrical Thienopentalenes: Synthesis, Optoelectronic Properties, and (Anti)aromaticity Analysis
Tamás Gazdag, Péter J. Mayer, Péter Pál Kalapos, Tamás Holczbauer, Ouissam El Bakouri, Gábor London
Abstract
H NMR and UV-vis spectroscopies, cyclic voltammetry, and X-ray crystallography, and their aromatic character was assessed using magnetic (NICS and ACID) and electronic indices (MCI and FLU).
Topics & Concepts
PentaleneAromaticityAntiaromaticityChemistryThiopheneCyclic voltammetryMoleculeProton NMRCrystallographyPhotochemistryStereochemistryComputational chemistryCombinatorial chemistryElectrochemistryOrganic chemistryPhysical chemistryElectrodeSynthesis and Properties of Aromatic CompoundsCatalytic Alkyne ReactionsCyclopropane Reaction Mechanisms