Self-regulated catalysis for the selective synthesis of primary amines from carbonyl compounds
Mingxia Gao, Xiuquan Jia, Jiping Ma, Xiaomeng Fan, Jin Gao, Jie Xu
Abstract
An Ru catalyst supported on the edge surface of hexagonal boron nitride (Ru/BN-e) demonstrates self-acceleration kinetics in the reductive amination reactions of carbonyl compounds under a low ammonia-to-substrate ratio.
Topics & Concepts
CatalysisReductive aminationChemistryAminationPrimary (astronomy)Substrate (aquarium)Hexagonal boron nitrideAmmoniaAmmonia productionBoronRutheniumOrganic chemistryCombinatorial chemistryMaterials scienceNanotechnologyGrapheneAstronomyGeologyOceanographyPhysicsAmmonia Synthesis and Nitrogen ReductionCovalent Organic Framework ApplicationsAdvanced Photocatalysis Techniques