Water sensitivity of heteroepitaxial Cu-MOF films: dissolution and re-crystallization of 3D-oriented MOF superstructures
Lea A. Brandner, Mercedes Linares‐Moreau, Guojun Zhou, Heinz Amenitsch, Simone Dal Zilio, Zhehao Huang, Christian J. Doonan, Paolo Falcaro
Abstract
We report the effect of humidity on oriented Cu-MOF films, including the epitaxial transformation of 3D-oriented Cu 2 (BDC) 2 DABCO into 3D-oriented Cu 2 (BDC) 2 .
Topics & Concepts
CrystallizationDissolutionMaterials scienceChemical engineeringEpitaxyDABCOMetal-organic frameworkHumidityCrystallographyNanotechnologyChemistryPhysical chemistryOrganic chemistryCatalysisAdsorptionLayer (electronics)PhysicsThermodynamicsEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsZnO doping and propertiesCopper-based nanomaterials and applications