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Stepped-Type Photoacoustic Resonator for Simultaneous Dual-Gas Detection

Chun Sun, Tianhe Yang, Jingya Zhang, Heng Wang, Bingyu Mo, Hongchao Qi, Ke Chen

2026Analytical Chemistry8 citationsDOI

Abstract

A stepped-type resonator-based photoacoustic (PA) sensor is proposed for simultaneous dual-gas detection. The sensor employs a dual-resonance architecture, with a stepped resonant tube capable of acoustic amplification at two different frequencies. An optimized design of the PA resonator response is conducted using finite element analysis. When the amplitudes of the two resonance peaks are high and the relative signal strength is also high, the simulated values of the two resonance frequencies are 2370 and 4220 Hz, respectively. A dual-channel synchronous digital lock-in amplifier is employed to achieve simultaneous detection in the two channels. Two lasers for methane and acetylene detection are modulated simultaneously, with the modulation frequencies set to half of these two resonant frequencies. The crosstalk evaluation results show that the signal crosstalk between the dual-gas detection channels is −125.26 dB, and the frequency crosstalk is −129.70 dB. Under a 1-s integration time, the minimum detection limits are 25.2 ppb for C 2 H 2 and 51.5 ppb for CH 4, corresponding to normalized noise-equivalent absorption coefficients (NNEAs) of 1.62 × 10 –9 Wcm – 1 Hz – 1/2 and 9.98 × 10 –10 Wcm – 1 Hz – 1/2, respectively.

Topics & Concepts

ResonatorChemistryPhotoacoustic imaging in biomedicineAmplifierLaserResonance (particle physics)Photoacoustic spectroscopyTime delay and integrationDetection limitCrosstalkAmplitudeOpticsOptoelectronicsSIGNAL (programming language)Amplitude modulationFrequency modulationMicrophoneAnalytical Chemistry (journal)Frequency responsePhotoacoustic effectDetection theorySpectroscopy and Laser ApplicationsPhotoacoustic and Ultrasonic ImagingCombustion and flame dynamics