Electrically conductive laser-induced graphene engraved Janus membrane for membrane distillation
Farah Rahman Omi, Masoud Rastgar, Afrouz Yousefi, Mojtaba Mohseni, Waralee Dilokekunakul, Matthias Weßling, Mohtada Sadrzadeh
Abstract
Electrically conductive membranes (ECMs) show significant potential in overcoming wetting and pore-blocking challenges in membrane distillation (MD) processes. In this study, a novel Janus ECM has been developed by laser-induced graphene (LIG) engraving technique on a polyamide-imide (PAI) membrane, complemented by a silica-infused PVDF layer on the opposite side to create a unique 'sandwich' structure. The Janus structure integrates the hydrophilicity of the LIG layer with the hydrophobicity of the PVDF layer, facilitating efficient vapor flux. The optimized membrane achieved electrical conductivity of 142 ± 1.5 S/cm, water vapor flux of 11.3 ± 0.56 LMH, and 99.77 ± 0.1 % salt rejection. Its underwater oleophobicity effectively resisted wetting by surfactants and oil-water emulsions. Furthermore, applying a cathodic potential of 3V enhanced the electrostatic interactions between organic foulants and the membrane surface, reducing fouling and achieving a minimal flux decline of 2.45 %/hr over 6 h. Experiments on mineral scaling mitigation revealed that AC electric fields outperformed DC fields. A square waveform at 5Hz frequency achieved over 99 % salt rejection with minimal flux decline for monovalent and multivalent ion solutions, attributed to enhanced electrophoretic mixing under the AC field. A long-term test with the monovalent salt solution under AC/1V/5Hz(square waveform) exhibited excellent flux with a minimum flux decline of 1.35 %/hr after 18 h of experiment with no significant change in the membrane LIG structure. The in-situ LIG engraving process and the membrane's adaptability to varying electric field applications highlight its potential for large-scale use. • In-situ LIG engraving offers a scalable method for creating LIG on membranes, enhancing stability and morphology control. • Janus membrane design integrates hydrophilic LIG and hydrophobic PVDF, optimizing vapor transport and preventing wetting. • Electric conductivity of LIG enables electric field applications to reduce fouling, scaling, and pollutant degradation. • The membrane delivers superior antifouling properties, high flux, and scalability for efficient water treatment. • The multifunctional nature of the LIG-based membrane allows applications in energy storage, sensors, and catalysis.