Diiron azadithiolate clusters supported on carbon nanotubes for efficient electrocatalytic proton reduction
Pei‐Hua Zhao, Jian‐Rong Li, Zhongyi Ma, Hongfei Han, Yongping Qu, Baoping Lu
Abstract
The first example of diiron azadithiolate clusters supported on carbon nanotubes (<bold>1-f-SWCNTs</bold>) was constructed <italic>via</italic> covalent attachment. This nanohybrid shows efficient electrocatalytic proton reduction with a TOF of 9444 s<sup>−1</sup> in 0.2 N aqueous H<sub>2</sub>SO<sub>4</sub>.
Topics & Concepts
Carbon nanotubeCovalent bondProtonAqueous solutionCarbon fibersElectrocatalystChemistryMaterials scienceElectrochemistryNanotechnologyPhysical chemistryOrganic chemistryElectrodePhysicsComposite materialComposite numberQuantum mechanicsElectrocatalysts for Energy ConversionMetalloenzymes and iron-sulfur proteinsAdvanced battery technologies research