4f → 3d sensitization: a luminescent Eu<sup>II</sup>–Mn<sup>II</sup> heteronuclear complex with a near-unity quantum yield
Gang Yu, Huanyu Liu, Wenchao Yan, Ruoyao Guo, Aoben Wu, Zifeng Zhao, Zhiwei Liu, Zuqiang Bian
Abstract
A new heteronuclear Eu II –Mn II complex with high photoluminescence quantum yield is designed and synthesized, which represents the first example of f → d molecular sensitization.
Topics & Concepts
Heteronuclear moleculeQuantum yieldYield (engineering)LuminescenceMaterials sciencePhysicsChemistryCrystallographyNuclear magnetic resonance spectroscopyNuclear magnetic resonanceFluorescenceOptoelectronicsQuantum mechanicsMetallurgyLanthanide and Transition Metal ComplexesMagnetism in coordination complexesElectron Spin Resonance Studies