Litcius/Paper detail

Pyrazine-bridged Cu(<scp>ii</scp>) chains: diaquabis(<i>n</i>-methyl-2-pyridone)copper(<scp>ii</scp>) perchlorate complexes

Emma Kirkman-Davis, Faith E. Witkos, Veli Selmani, Jeffrey C. Monroe, Christopher P. Landee, Mark M. Turnbull, Louise N. Dawe, Matthew I. J. Polson, Jan L. Wikaira

2020Dalton Transactions13 citationsDOI

Abstract

Reaction of pz, Cu(ClO<sub>4</sub>)<sub>2</sub> and <italic>n</italic>-Me-2(1<italic>H</italic>)-pyridone (L) makes a family of <italic>S</italic> = ½, AFM chains [CuL<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>pz](ClO<sub>4</sub>)<sub>2</sub>. The compounds were studied by crystallography, EPR and magnetic susceptibility showing a correlation with the Jahn–Teller axis.

Topics & Concepts

PyrazineCrystallographyChemistryPerchlorateHydrogen bondIntramolecular forceMoleculeTautomerMagnetic susceptibility2-PyridoneCopperElectron paramagnetic resonancePyridineAntiferromagnetismStereochemistryIonMedicinal chemistryNuclear magnetic resonanceOrganic chemistryCondensed matter physicsPhysicsMagnetism in coordination complexesMetal complexes synthesis and propertiesLanthanide and Transition Metal Complexes