Reversibly photoswitchable catalysts for high regioselectivity and enantioselectivity in polymerization of allenes
Li Zhou, Yong‐Jie Wu, Kun Chen, Xing-Yu Zhou, Hui Zou, Shu‐Ming Kang, Na Liu, Zong‐Quan Wu
Abstract
Two enantiomers Ni( ii )/ L R -azo and Ni( ii )/ L S -azo could be used as reversible photo-switchable catalysts for the high regioselectivity and enantioselectivity polymerization of allene monomers.
Topics & Concepts
RegioselectivityAlleneChemistryPolymerizationCatalysisMonomerEnantiomerPolymer chemistryPhotochemistryOrganic chemistryPolymerPhotochromic and Fluorescence ChemistryClick Chemistry and ApplicationsAdvanced Polymer Synthesis and Characterization