Structure:function relationships for thermal and light-induced spin-crossover in isomorphous molecular materials
Rafał Kulmaczewski, Elżbieta Trzop, Éric Collet, Sergi Vela, Malcolm A. Halcrow
Abstract
The complicated light-induced spin state trapping behaviour of a family of isomorphous solvate crystals reflects reorientation of the lattice solvent during the spin-transition (white = high-spin, brown = low-spin).
Topics & Concepts
Spin crossoverMaterials scienceCondensed matter physicsSpin (aerodynamics)ThermalSpin statesLattice (music)TrappingFrustrationSpin transitionCrystallographyChemical physicsChemistryThermodynamicsPhysicsBiologyAcousticsEcologyMagnetism in coordination complexesLanthanide and Transition Metal ComplexesAdvanced NMR Techniques and Applications