A unified pH scale for all solvents: part I – intention and reasoning (IUPAC Technical Report)
Valentin Radtke, Daniela Stoica, Ivo Leito, Maria Filomena Camões, Ingo Krossing, Bárbara Anes, Matilda Roziková, Lisa Deleebeeck, S. Veltzé, Teemu Näykki, Frank Bastkowski, Agnes Heering, Dániel Nagy, Raquel Quendera, Lokman Liv, Emrah Uysal, Nathan S. Lawrence
Abstract
Abstract The definition of pH, its measurement and standard buffers, is well developed in aqueous solutions. Its definition in solvents other than water has been elaborated for a couple of solvents and their mixtures with water. However, the definition of a universal pH scale spanning all solvents and phases, not to mention standard procedures of measurement, is still a largely uncharted territory. UnipHied is a European collaboration and has the goal of putting the theoretical concept of an earlier introduced (2010) unified pH abs scale on a metrologically well-founded basis into practice. The pH abs scale enables the comparability of acidity between different phases. This article draws the connection of the concepts of unified acidity and secondary pH measurement.