Chlorophyll Detection by Localized Surface Plasmon Resonance Using Functionalized Carbon Quantum Dots Triangle Ag Nanoparticles
Nur Afifah Ahmad Nazri, Nur Hidayah Azeman, Mohd Hafiz Abu Bakar, Nadhratun Naiim Mobarak, Tg Hasnan Tg Abd Aziz, Ahmad Rifqi Md Zain, Norhana Arsad, Yunhan Luo, Ahmad Ashrif A. Bakar
Abstract
An optical sensor-based localized surface plasmon resonance (LSPR) sensor was demonstrated for sensitive and selective chlorophyll detection through the integration of amino-functionalized carbon quantum dots (NCQD) and triangle silver nanoparticles (AgNPs). The additions of amino groups to the CQD enhance the detection of chlorophyll through electrostatic interactions. AgNPs-NCQD composite was fabricated on the surface of the silanized glass slide using the self-assembly technique. The experimental results showed that the AgNPs-NCQD film-based LSPR sensor detects better than AgNPs and AgNPs-CQD films with a good correlation coefficient (R2 = 0.9835). AgNPs-NCQD showed a high sensitivity response of 2.23 nm ppm−1. The detection and quantification limits of AgNPs-NCQD are 1.03 ppm and 3.40 ppm, respectively, in the range of 0.05 to 6 ppm. Throughout this study, no significant interference was observed among the other ionic species (NO2−, PO4−, NH4+, and Fe3+). This study demonstrates the applicability of the proposed sensor (AgNPs-NCQD) as a sensing material for chlorophyll detection in oceans.