Tailoring adsorption induced switchability of a pillared layer MOF by crystal size engineering
Leila Abylgazina, Irena Senkovska, Sebastian Ehrling, Volodymyr Bon, Petko St. Petkov, Jack D. Evans, S. N. Krylova, А. С. Крылов, Stefan Kaskel
Abstract
The main factors affecting switchability are identified for DUT-8(Zn): energetics of the host, particle size, and desolvation stress. They influence the flexible behaviour to the same order of magnitude and should be always considered collectively.
Topics & Concepts
AdsorptionMaterials scienceParticle sizeLayer (electronics)Chemical engineeringCrystal (programming language)Crystal engineeringStress (linguistics)Particle (ecology)NanotechnologyCrystallographyCrystal structureChemistryPhysical chemistryComputer scienceEngineeringGeologySupramolecular chemistryPhilosophyOceanographyProgramming languageLinguisticsMetal-Organic Frameworks: Synthesis and ApplicationsZnO doping and propertiesMetal Extraction and Bioleaching