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An ATP responsive fluorescent supramolecular assembly based on a polyelectrolyte and an AIE active tetraphenylethylene derivative

Vidya R. Singh, Jotiram N. Malegaonkar, Sidhanath V. Bhosale, Prabhat K. Singh

2020Organic & Biomolecular Chemistry33 citationsDOI

Abstract

H NMR measurements. The Su-TPE-PAH aggregate assembly is found to be responsive towards the ionic strength of the medium and temperature which results in drastic modulations of the spectral features of the emissive supramolecular aggregate assembly. Finally, the specific recognition of an important bioanalyte, ATP, has been achieved using the formed Su-TPE-PAH supramolecular aggregate assembly as a sensing platform which displays good selectivity and high sensitivity towards ATP. Importantly, the developed sensor platform could also function in the human serum matrix, hence, demonstrating the potential of the established sensor platform for real-life applications in near future.

Topics & Concepts

TetraphenylethyleneCationic polymerizationSupramolecular chemistryChemistryFluorescenceMoleculeSupramolecular assemblyPhotochemistryPolyelectrolyteMonomerCombinatorial chemistryAggregation-induced emissionPolymer chemistryOrganic chemistryPolymerPhysicsQuantum mechanicsMolecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsSupramolecular Chemistry and Complexes
An ATP responsive fluorescent supramolecular assembly based on a polyelectrolyte and an AIE active tetraphenylethylene derivative | Litcius