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Understanding solid electrolyte interface formation on graphite and silicon anodes in lithium-ion batteries: Exploring the role of fluoroethylene carbonate

Jinhee Lee, Ji-Yoon Jeong, Jaeyun Ha, Yong‐Tae Kim, Jinsub Choi

2024Electrochemistry Communications27 citationsDOIOpen Access PDF

Abstract

This study explores how fluoroethylene carbonate (FEC) influences the solid electrolyte interface (SEI) layer formation during battery charging process. FEC improves SEI properties, producing a uniform, chemically stable layer enriched with lithium fluoride. This enhances mechanical resilience and electrochemical stability. FEC also suppresses electrolyte deformation and decomposition, maintaining its initial state. The findings highlight the significance and comprehension of electrolyte additives, offering an electrolyte research pathway for improving Li-ion battery performance and durability.

Topics & Concepts

ElectrolyteGraphiteLithium (medication)AnodeInorganic chemistrySiliconCarbonateIonElectrochemistryChemistryMaterials scienceElectrodePhysical chemistryOrganic chemistryEndocrinologyMedicineAdvancements in Battery MaterialsAdvanced Battery Materials and TechnologiesAdvanced Battery Technologies Research