Synthesis and rhodium complexes of macrocyclic PNP and PONOP pincer ligands
Thomas M. Hood, Matthew R. Gyton, Adrian B. Chaplin
Abstract
). Subsequent hydrogenolysis enabled generation of dihydrogen, ethylene and carbonyl derivatives; notably the ν(CO) bands of the carbonyl complexes provide a means to compare the donor properties of the new pincer ligands with established acyclic congeners.
Topics & Concepts
Pincer movementRhodiumChemistryPincer ligandCombinatorial chemistryStereochemistryCatalysisOrganic chemistryOrganometallic Complex Synthesis and CatalysisCatalytic Cross-Coupling ReactionsCarbon dioxide utilization in catalysis