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Active Site Sequence Representations of Human Kinases Outperform Full Sequence Representations for Affinity Prediction and Inhibitor Generation: 3D Effects in a 1D Model

Jannis Born, Toan Huynh, Astrid Stroobants, Wendy D. Cornell, Matteo Manica

2021Journal of Chemical Information and Modeling29 citationsDOIOpen Access PDF

Abstract

for both unseen ligands and kinases. Our interpretability analysis reveals a potential explanation for the superiority of the active site models: whereas only mild statistical effects about the extraction of three-dimensional (3D) interaction sites take place in the full sequence models, the active site models are equipped with an implicit but strong inductive bias about the 3D structure stemming from the discontiguity of the active sites. Moreover, in direct comparisons, our models perform similarly or better than previous state-of-the-art approaches in affinity prediction. We then investigate a de novo molecular design task and find that the active site provides benefits in the computational efficiency, but otherwise, both kinase representations yield similar optimized affinities (for both SMILES- and SELFIES-based molecular generators). Our work challenges the assumption that the full primary structure is indispensable for modeling human kinases.

Topics & Concepts

InterpretabilityKinomeSequence (biology)Computational biologyComputer scienceArtificial intelligenceActive siteBinding siteVirtual screeningRepresentation (politics)Drug discoveryMachine learningKinaseBiologyBioinformaticsBiochemistryEnzymePoliticsLawPolitical scienceComputational Drug Discovery MethodsProtein Structure and DynamicsMicrobial Natural Products and Biosynthesis