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An extended conformation of SARS-CoV-2 main protease reveals allosteric targets

Zengchao Sun, Lu Wang, Xiyang Li, Chengpeng Fan, Jianfeng Xu, Zhenzhong Shi, Huarui Qiao, Zhongyun Lan, Xin Zhang, Lingyun Li, Xin Zhou, Yong Geng

2022Proceedings of the National Academy of Sciences34 citationsDOIOpen Access PDF

Abstract

Significance The coronavirus main protease (M pro ) is required for viral replication. Here, we obtained the extended conformation of the native monomer of severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) M pro by trapping it with nanobodies and found that the catalytic domain and the helix domain dissociate, revealing allosteric targets. Another monomeric state is termed compact conformation and is similar to one protomer of the dimeric form. We designed a Nanoluc Binary Techonology (NanoBiT)-based high-throughput allosteric inhibitor assay based on structural conformational change. Our results provide insight into the maturation, dimerization, and catalysis of the coronavirus M pro and pave a way to develop an anticoronaviral drug through targeting the maturation process to inhibit the autocleavage of M pro .

Topics & Concepts

Allosteric regulationChemistryProteaseCoronavirusMonomerSevere acute respiratory syndrome coronavirus 2 (SARS-CoV-2)Protein structureStereochemistryStructural biologyBiophysicsComputational biologyCoronavirus disease 2019 (COVID-19)BiochemistryEnzymeBiologyPolymerMedicinePathologyOrganic chemistryDiseaseInfectious disease (medical specialty)SARS-CoV-2 and COVID-19 ResearchAdvanced biosensing and bioanalysis techniquesvaccines and immunoinformatics approaches