Ultrahigh Efficiency LiAlGa<sub>4</sub>O<sub>8</sub>: Cr<sup>3+</sup>, Ni<sup>2+</sup> Near-Infrared Phosphor with an External Photoluminescence Quantum Yield Exceeding 70% via Cr<sup>3+</sup>–Ni<sup>2+</sup> Energy Transfer
Wendong Nie, Sisi Liang, Dejian Chen, Jie Hu, Zihao Wang, Zixin Pan, Hongyi Yang, Fulin Lin, Xiaodong Yi, Haomiao Zhu
Abstract
Ni 2+ -doped inorganic crystals are promising for generating broadband emissions from 1000 to 1700 nm, which are crucial for advancing NIR light sources. However, their commercial applications have been hindered due to their weak absorption. Herein, the LiAl 5 O 8 crystal is present as the host for Cr 3+ and Ni 2+ ions due to its high density of available doping sites (Al 3+ ) per unit volume (0.048/Å 3 ) for Cr 3+ sensitizers. By heavily increasing the doping concentration of Cr 3+, an unprecedented broad emission band peaking at 773 nm emerges, enhancing the spectral overlap between the emission of Cr 3+ and absorption of Ni 2+, thus boosting the energy transfer efficiency from Cr 3+ to Ni 2+ . This accelerated energy transfer rate competes favorably against nonradiative processes, allowing higher concentrations of Cr 3+ without any photoluminescence quenching. Moreover, by substituting Ga 3+ for Al 3+, the excitation peak is successfully tuned from 405 to 445 nm, aligning perfectly with commercial blue diode chips. As a result, the optimal LiAlGa 4 O 8: 0.26Cr 3+, 0.1Ni 2+ phosphor exhibits a broadband emission ranging from 950 to 1600 nm, achieving internal/external photoluminescence quantum yields up to 94.12 and 72.62%, respectively. The application demonstration of packaged lighting devices shows its great potential in the fields of poultry farming and life science.