3D Nitrogen‐Doped Graphene Encapsulated Metallic Nickel–Iron Alloy Nanoparticles for Efficient Bifunctional Oxygen Electrocatalysis
Zhaoyang Wang, Xiaobin Liao, Zifeng Lin, Fuzhi Huang, Yalong Jiang, Kwadwo Asare Owusu, Lin Xu, Ziang Liu, Jiantao Li, Yan Zhao, Yi‐Bing Cheng, Liqiang Mai
Abstract
Abstract It is extremely desirable to explore high‐efficient, affordable and robust oxygen electrocatalysts toward rechargeable Zn–air batteries (ZABs). A 3D porous nitrogen‐doped graphene encapsulated metallic Ni 3 Fe alloy nanoparticles aerogel (Ni 3 Fe‐GA 1 ) was constructed through a facile hydrothermal assembly and calcination process. Benefiting from 3D porous configuration with great accessibility, high electrical conductivity, abundant active sites, optimal nitrogen content and strong electronic interactions at the Ni 3 Fe/N‐doped graphene heterointerface, the obtained aerogel showed outstanding catalytic performance toward the oxygen evolution reaction (OER) and oxygen reduction reaction (ORR). Specifically, it exhibited an overpotential of 239 mV to attain 10 mA cm −2 for OER, simultaneously providing a positive onset potential of 0.93 V within a half‐wave potential of 0.8 V for ORR. Accordingly, when employed in the aqueous ZABs, Ni 3 Fe‐GA 1 achieved higher power density and superior reversibility than Pt/C−IrO 2 catalyst, making it a potential candidate for rechargeable ZABs.