Heavier group 13/15 multiple bond systems: synthesis, structure and chemical bond activation
Fabian Dankert, Christian Hering‐Junghans
Abstract
) (Pn = P, As) in combination with Al(I) synthons afforded the first examples of phospha- and arsaalumenes as isolable and thermally robust compounds. This feature article is intended to show the recent developments in the field, to outline early synthetic approaches and to discuss strategies to unlock the synthetic potential of these elusive chemical bonds.
Topics & Concepts
SynthonGroup (periodic table)ChemistryBondChemical bondDouble bondMoleculeCombinatorial chemistryStereochemistryOrganic chemistryBusinessFinanceSynthesis and characterization of novel inorganic/organometallic compoundsCoordination Chemistry and OrganometallicsOrganoboron and organosilicon chemistry