Geminal bimetallic coordination of a carbone to main-group and transition metals
D. Akachukwu, Chun‐Lin Deng, Andrew J. H. Alexis, Diane A. Dickie, Robert J. Gilliard
Abstract
The non-bonding carbone lone pair in geometrically-constrained antimony and bismuth carbodiphosphorane complexes readily complexed AuCl to afford rare examples of geminal bimetallic carbone coordination featuring a main-group metal.
Topics & Concepts
GeminalBimetallic stripTransition metalGroup (periodic table)Coordination complexChemistryMetalInorganic chemistryMaterials scienceCrystallographyCatalysisStereochemistryOrganic chemistryMetal-Organic Frameworks: Synthesis and ApplicationsOrganometallic Complex Synthesis and CatalysisMagnetism in coordination complexes