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Reduction of dislocation density in α-Ga<sub>2</sub>O<sub>3</sub> epilayers via rapid growth at low temperatures by halide vapor phase epitaxy

Yuichi Oshima, Hiroyuki Ando, Takashi Shinohe

2023Applied Physics Express13 citationsDOIOpen Access PDF

Abstract

Abstract We demonstrate that the dislocation density in α -Ga 2 O 3 epilayers is markedly reduced via rapid growth at low temperatures by halide vapor-phase epitaxy. An α -Ga 2 O 3 epilayer grown on (0001) sapphire at a high growth rate of 34 μ m h −1 and a low temperature of 463 °C exhibited a dislocation density of 4 × 10 8 cm −2 , which was approximately 1/100 of that in a conventional film. It is likely that the three-dimensional surface morphology developed during the growth enhanced the bending of the dislocations to increase the probability of pair annihilation. The combination of this technique with thick film growth and epitaxial lateral overgrowth resulted in a further low dislocation density of 1.1 × 10 7 cm −2 .

Topics & Concepts

EpitaxyDislocationMaterials scienceSapphireHalideVapor phasePhase (matter)Growth rateMorphology (biology)Analytical Chemistry (journal)CrystallographyOptoelectronicsOpticsChemistryNanotechnologyComposite materialInorganic chemistryThermodynamicsGeometryLaserLayer (electronics)GeneticsOrganic chemistryBiologyMathematicsPhysicsChromatographyGa2O3 and related materialsZnO doping and propertiesAdvanced Photocatalysis Techniques
Reduction of dislocation density in α-Ga<sub>2</sub>O<sub>3</sub> epilayers via rapid growth at low temperatures by halide vapor phase epitaxy | Litcius