Litcius/Paper detail

On the use of catalysis to bias reaction pathways in out-of-equilibrium systems

Michelle P. van der Helm, Tuanke de Beun, Rienk Eelkema

2021Chemical Science34 citationsDOIOpen Access PDF

Abstract

up or downregulation of catalysts' levels temporarily changes the product steady state, whereas feedback elements can give unusual concentration profiles as a function of time and self-regulation in a CRN. We show that simulations can be highly effective in predicting CRN behavior. In the future, shifting the focus from enzyme catalysis towards small molecule and metal catalysis in out-of-equilibrium systems can provide us with new reaction networks and enhance their application potential in synthetic materials, overall advancing the design of man-made responsive and interactive systems.

Topics & Concepts

CatalysisChemistryBiochemical engineeringComputational chemistryOrganic chemistryEngineeringMolecular Junctions and NanostructuresSurface Chemistry and CatalysisSpectroscopy and Quantum Chemical Studies