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The Gas-phase Reaction of NH<sub>2</sub> with Formaldehyde (CH<sub>2</sub>O) is not a Source of Formamide (NH<sub>2</sub>CHO) in Interstellar Environments

Kevin M. Douglas, Daniel I. Lucas, Catherine Walsh, Niclas A. West, Mark A. Blitz, Dwayne E. Heard

2022The Astrophysical Journal Letters35 citationsDOIOpen Access PDF

Abstract

Abstract The first experimental study of the low-temperature kinetics of the gas-phase reaction of NH 2 with formaldehyde (CH 2 O) has been performed. This reaction has previously been suggested as a source of formamide (NH 2 CHO) in interstellar environments. A pulsed Laval nozzle equipped with laser-flash photolysis and laser-induced fluorescence spectroscopy was used to create and monitor the temporal decay of NH 2 in the presence of CH 2 O. No loss of NH 2 could be observed via reaction with CH 2 O, and we place an upper limit on the rate coefficient of &lt;6 × 10 −12 cm 3 molecule −1 s −1 at 34 K. Ab initio calculations of the potential energy surface were combined with Rice–Rampsberger–Kassel–Marcus (RRKM) calculations to predict a rate coefficient of 6.2 × 10 −14 cm 3 molecule −1 s −1 at 35 K, consistent with the experimental results. The presence of a significant barrier, 18 kJ mol −1 , for the formation of formamide as a product, means that only the H-abstraction channel producing NH 3 + CHO, in which the transfer of an H atom can occur by quantum mechanical tunneling through a 23 kJ mol −1 barrier, is open at low temperatures. These results are in contrast with a recent theoretical study, which suggested that the reaction could proceed without a barrier and was therefore a viable route to gas-phase formamide formation. The calculated rate coefficients were used in an astrochemical model, which demonstrated that this reaction produces only negligible amounts of gas-phase formamide under interstellar and circumstellar conditions. The reaction of NH 2 with CH 2 O is therefore not an important source of formamide at low temperatures in interstellar environments.

Topics & Concepts

FormamideFormaldehydeAb initioChemistryFlash photolysisReaction rate constantPotential energy surfaceQuantum tunnellingPhysical chemistryReaction rateMoleculeChemical kineticsKineticsPhotochemistryAnalytical Chemistry (journal)PhysicsOrganic chemistryOptoelectronicsQuantum mechanicsCatalysisAdvanced Chemical Physics StudiesAstrophysics and Star Formation StudiesMolecular Spectroscopy and Structure
The Gas-phase Reaction of NH<sub>2</sub> with Formaldehyde (CH<sub>2</sub>O) is not a Source of Formamide (NH<sub>2</sub>CHO) in Interstellar Environments | Litcius