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Temporal Dynamics of Reactive CO <sub>2</sub> Flow in Carbonate Rock: Insights from 4D Synchrotron Imaging

Azibayam Josiah Amabogha, Amin Taghavinejad, Waleed Dokhon, Shashidhara Marathe, Lin Ma, Branko Bijeljic, Martin J. Blunt, Muhammad Arif, Yihuai Zhang

2025Energy & Fuels7 citationsDOIOpen Access PDF

Abstract

-saturated brine through the sample with in situ scanning to track the different stages of chemical dissolution. Analysis of the images shows a channelled dissolution pattern which corresponds with a gradual increase in porosity due to pore structure changes. Pore network models were generated from the segmented images to carry out a sequence of drainage and imbibition simulations. The result demonstrated that reduced capillary entry pressure with increased pore connectivity after dissolution. Furthermore, the trapping efficiency was quantified to predict a slight decrease in dissolution as the pores become broader and better connected.

Topics & Concepts

CarbonateSynchrotronDissolutionImbibitionMineralogyPorosityPorous mediumPore water pressureBrineCapillary actionTRACERIn situChemical physicsMaterials scienceFlow (mathematics)GeologyCalcium carbonateChemistryCarbonate rockCurvatureAnalytical Chemistry (journal)Raman spectroscopyQuartzFluid dynamicsCapillary pressureDiamond anvil cellSynchrotron radiationPartial pressureTrappingChemical engineeringAmbient pressureChemical reactionEnhanced Oil Recovery TechniquesCO2 Sequestration and Geologic InteractionsHydrocarbon exploration and reservoir analysis
Temporal Dynamics of Reactive CO <sub>2</sub> Flow in Carbonate Rock: Insights from 4D Synchrotron Imaging | Litcius