Lithium ion diffusion mechanism on the inorganic components of the solid–electrolyte interphase
Jianhui Zheng, Zhijin Ju, Baolin Zhang, Jianwei Nai, Tiefeng Liu, Yujing Liu, Qifan Xie, Wenkui Zhang, Yao Wang, Xinyong Tao
Abstract
The inorganic nanocrystals (LiOH, Li<sub>2</sub>O, Li<sub>2</sub>CO<sub>3</sub>, LiF) embedded in the amorphous organic phase forming a mosaic structure. We discovered that LiF surface presents the fastest diffusion rate for Li ions due to the relative lower energy barriers.
Topics & Concepts
DiffusionLithium (medication)Amorphous solidIonElectrolyteNanocrystalInterphaseMaterials sciencePhase (matter)Chemical engineeringSurface diffusionInorganic chemistryChemistryNanotechnologyCrystallographyPhysical chemistryAdsorptionElectrodeThermodynamicsOrganic chemistryGeneticsEngineeringPhysicsMedicineEndocrinologyBiologyAdvanced Battery Materials and TechnologiesAdvancements in Battery MaterialsConducting polymers and applications