Photoelectrochemical nickel-catalyzed carboacylation/silanoylation of alkenes with unactivated C/Si–H bonds
Lanfen Wang, Xiangyu Huo, Xiao‐Zhi He, Lutz Ackermann, Dingyi Wang
Abstract
A photoelectrochemical approach for the carboacylation/silanoylation of alkenes with alkanes/hydrosilanes is described. The method offers a new perspective for chemists to rapidly obtain various ketones with high levels of structural complexity.
Topics & Concepts
CatalysisNickelChemistryCombinatorial chemistryPhotochemistryOrganic chemistryCatalytic C–H Functionalization MethodsRadical Photochemical ReactionsSulfur-Based Synthesis Techniques