Mechanistic insights on the epoxidation of alkenes by high-valent non-heme Fe(<scp>iv</scp>) and Fe(<scp>v</scp>) oxidants: a comparative theoretical study
Oval Yadav, Manjeet Kumar, Ranjan K. Mohapatra, Manoj K. Gupta, Mursaleem Ansari, Azaj Ansari
Abstract
This work is based on the screening of better high-valent oxidants, and also includes a mechanistic study during oxygen atom transfer reactions.
Topics & Concepts
ChemistryHemeStereochemistryMedicinal chemistryOrganic chemistryEnzymeMetal-Catalyzed Oxygenation MechanismsPorphyrin and Phthalocyanine ChemistryOxidative Organic Chemistry Reactions