Radical relay cyclization/C–C bond formation of allyloxy-tethered aryl iodides with quinoxalin-2(1<i>H</i>)-ones <i>via</i> polysulfide anion photocatalysis
Zhongyi Zhang, Yaqin Zhou, Jiehui Wang, Yicheng Zhang, Lei Wang, Jie Liu, Chao Zhou, Min Wang, Pinhua Li
Abstract
A visible-light-induced radical relay cyclization/C–C bond formation of quinoxalin-2(1 H )-ones with allyloxy-tethered aryl iodides using polysulfide anions as a photocatalyst is described.
Topics & Concepts
PolysulfideRelayChemistryArylPhotocatalysisPhotochemistryRadical cyclizationIonMedicinal chemistryCatalysisPower (physics)Organic chemistryAlkylElectrodePhysicsQuantum mechanicsPhysical chemistryElectrolyteRadical Photochemical ReactionsSulfur-Based Synthesis TechniquesCatalytic C–H Functionalization Methods