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Flowery ln2MnSe4 Novel Electrocatalyst Developed via Anion Exchange Strategy for Efficient Water Splitting

Sumaira Manzoor, Sergei V. Trukhanov, Mohammad Numair Ansari, Muhammad Abdullah, Atalah Alruwaili, А.В. Труханов, Mayeen Uddin Khandaker, Abubakr M. Idris, Karam S. El‐Nasser, T.A. Taha

2022Nanomaterials80 citationsDOIOpen Access PDF

Abstract

Oxygen and hydrogen generated by water electrolysis may be utilized as a clean chemical fuel with high gravimetric energy density and energy conversion efficiency. The hydrogen fuel will be the alternative to traditional fossil fuels in the future, which are near to exhaustion and cause pollution. In the present study, flowery-shaped In2MnSe4 nanoelectrocatalyst is fabricated by anion exchange reaction directly grown on nickel foam (NF) in 1.0 M KOH medium for oxygen evolution reaction (OER). The physiochemical and electrical characterization techniques are used to investigate the chemical structure, morphology, and electrical properties of the In2MnSe4 material. The electrochemical result indicates that synthesized material exhibits a smaller value of Tafel slope (86 mV/dec), lower overpotential (259 mV), and high stability for 37 h with small deterioration in the current density for a long time. Hence, the fabricated material responds with an extraordinary performance for the OER process and for many other applications in the future.

Topics & Concepts

OverpotentialTafel equationElectrocatalystWater splittingOxygen evolutionElectrolysisExchange current densityGravimetric analysisChemical engineeringElectrolysis of waterElectrochemistryMaterials scienceAlkaline water electrolysisIon exchangeFossil fuelHydrogenInorganic chemistryChemistryCatalysisIonElectrodeElectrolyteOrganic chemistryPhysical chemistryPhotocatalysisEngineeringElectrocatalysts for Energy ConversionAdvanced Photocatalysis TechniquesAdvanced battery technologies research
Flowery ln2MnSe4 Novel Electrocatalyst Developed via Anion Exchange Strategy for Efficient Water Splitting | Litcius