Thermostability promotion of α-diimine nickel precatalysts tailored with 2,6-bis(bis(4-fluorophenyl)methyl)-3,4,5-trimethoxyaniline for PE elastomer synthesis
Zexu Hu, Geng Ren, Qaiser Mahmood, Zhixin Yu, Yizhou Wang, Kainat Fatima Tahir, Song Zou, Tongling Liang, Wen‐Hua Sun
Abstract
A set of five nonsymmetrical 1,2-bis(arylimino)acenaphthene–nickel complexes, incorporating 2,6-bis(bis(4-fluorophenyl)methyl)-3,4,5-trimethoxyaniline, was designed and prepared to tailor the catalytic attributes for ethylene polymerization.
Topics & Concepts
ChemistryThermostabilityDiimineNickelElastomerCatalysisOrganic chemistryPolymer chemistryEnzymeSynthesis and properties of polymersSilicone and Siloxane ChemistryPolymer Nanocomposites and Properties