Folding of fluorinated oligoarylenes into non-alternant PAHs with various topological shapes
Vladimir Akhmetov, Andreas Förtsch, Mikhail Feofanov, Sergey I. Troyanov, Konstantin Amsharov
Abstract
An unprecedented [6]helicene's cavity closure indicating the possibility of introducing seven-membered rings <italic>via</italic> alumina-mediated C–F activation is shown.
Topics & Concepts
ChemistryHeliceneClosure (psychology)Folding (DSP implementation)Topology (electrical circuits)CrystallographyComputational chemistryNanotechnologyMoleculeOrganic chemistryCombinatoricsMarket economyMathematicsEngineeringMaterials scienceElectrical engineeringEconomicsSynthesis and Properties of Aromatic CompoundsFullerene Chemistry and ApplicationsPorphyrin and Phthalocyanine Chemistry