Solvation effect on the ESIPT mechanism of nitrile-substituted <i>ortho</i>-hydroxy-2-phenyl-oxazolines
Hengwei Zhang, Wenzhi Li, Yuxi Wang, Yaping Tao, Yi Wang, Fan Yang, Ziqing Gao
Abstract
After photoexcitation, NOHPO could transform from enol to keto form spontaneously, and ESIPT progress was promoted with the decrease in polarity.
Topics & Concepts
NitrileSolvationChemistryMedicinal chemistryMechanism (biology)Computational chemistryOrganic chemistrySolventPhilosophyEpistemologyChemical Reaction MechanismsOrganic Chemistry Cycloaddition ReactionsFree Radicals and Antioxidants