Functional group substitution strongly influences the performances of covalent organic frameworks in the photocatalytic metal-free oxidase reaction
Huiying Chen, Qinghai Zhou, Jinyang Hai, Mingxiang Zhu, Fang Zhang
Abstract
Ten kinds of COFs were prepared with different functional groups to investigate structure–property–activity relationship. The crucial factor influencing the properties of COFs and reaction activity was the electron affinity of their initial monomers.
Topics & Concepts
Covalent bondPhotocatalysisChemistrySubstitution (logic)Group (periodic table)Functional groupPhotochemistryCombinatorial chemistryOrganic chemistryCatalysisComputer sciencePolymerProgramming languageCovalent Organic Framework ApplicationsAdvanced Nanomaterials in CatalysisMetal-Organic Frameworks: Synthesis and Applications