Eosin Y-Catalyzed Visible-Light-Induced Hydroperfluoroalkylation of Electron-Deficient Alkenes
Satsuki Shigenaga, Haruko Shibata, Koto Tagami, Tadashi Kanbara, Tomoko Yajima
Abstract
The eosin Y-catalyzed hydroperfluoroalkylation of electron-deficient alkenes is described herein. The reaction proceeded smoothly under visible light irradiation and selectively afforded a hydroperfluoroalkylated product. Various perfluoroalkyl bromides and electron-deficient olefins can be used in this reaction, and all chemicals required for this reaction are safe and readily available.
Topics & Concepts
Eosin YCatalysisEosinVisible spectrumPhotochemistryChemistryIrradiationCombinatorial chemistryOrganic chemistryPhotocatalysisMaterials scienceOptoelectronicsStainingPhysicsBiologyGeneticsNuclear physicsFluorine in Organic ChemistryRadical Photochemical ReactionsWeb Data Mining and Analysis