Binding of carbon dioxide and acetylene to free carboxylic acid sites in a metal–organic framework
Christopher Marsh, Xue Han, Zhenzhong Lu, Iván da Silva, Yongqiang Cheng, Luke L. Daemen, Sarah J. Day, Stephen P. Thompson, Anibal J. Ramirez‐Cuesta, Sihai Yang⧫, Martin Schröder
Abstract
Metal–organic frameworks incorporating free carboxylic acid and hydroxyl groups are beneficial for selective uptake of small molecules such as CO 2 and C 2 H 2 . This has been revealed through SXPD and INS/DFT studies.
Topics & Concepts
AcetyleneCarbon dioxideCarboxylic acidChemistryOrganic moleculesMoleculeMetalMetal-organic frameworkOrganic chemistryAdsorptionMetal-Organic Frameworks: Synthesis and ApplicationsCarbon dioxide utilization in catalysisZeolite Catalysis and Synthesis