High-nuclearity and thiol protected core–shell [Cu<sub>75</sub>(S-Adm)<sub>32</sub>]<sup>2+</sup>: distorted octahedra fixed to Cu<sub>15</sub> core <i>via</i> strong cuprophilic interactions
Jie Tang, Chong Liu, Chong Liu, Chenyu Zhu, Keju Sun, He Wang, Wen Yin, Chuting Xu, Yang Li, Weiguo Wang, Li Wang, Ren’an Wu, Chao Liu, Chao Liu, Jiahui Huang
Abstract
-S mode of S, which plays two roles as a vertex and bridge atom to connect Cu atoms. This work presents a unique nanoball Cu nanocluster with strong cuprophilic interaction and provides a novel method to expand the family of Cu nanoclusters as well.
Topics & Concepts
OctahedronCore (optical fiber)CrystallographyMaterials scienceThiolChemistryCrystal structureBiochemistryComposite materialNanocluster Synthesis and ApplicationsMetal complexes synthesis and propertiesMagnetism in coordination complexes