Catalytic asymmetric deuterosilylation of exocyclic olefins with mannose-derived thiols and deuterium oxide
Devenderan Ramanathan, Qinglong Shi, Meichen Xu, Rui Chang, Beatriz Peñín, Ignacio Funes‐Ardoiz, Juntao Ye
Abstract
Metal-free, photoinduced asymmetric deuterosilylation of exocyclic olefins has been achieved using a mannose-derived thiol catalyst.
Topics & Concepts
ChemistryCatalysisMannoseThiolDeuteriumOxideOrganic chemistryPhotochemistryPhysicsQuantum mechanicsChemical Reactions and IsotopesAsymmetric Hydrogenation and CatalysisChemical Synthesis and Analysis