Mechanochemistry: A Green and Fast Method to Prepare a New Generation of Metal Supported Catalysts
Maila Danielis, Sara Colussi, Núria J. Divins, Lluís Soler, Alessandro Trovarelli, Jordi Llorca
Abstract
In this review, we report on recent advances in the use of mechanochemistry to synthesise new catalytic materials. We report recent results obtained by our groups where a rational design of the milling parameters led to the synthesis of advanced materials with novel properties such as unconventional arrangements of metals on the surface of oxide support materials, highly dispersed metals or the stabilisation of species in particular oxidation states. These properties resulted in superior catalytic performances of the mechanochemically-synthesised catalysts compared to their counterparts prepared by traditional impregnation methods. To illustrate these advances, we review the progress made in two important fields of catalysis where noble metals are used: (i) emission control catalysis using palladium-based materials; (ii) the development of photocatalysts to produce hydrogen based on gold and palladium materials.