Leveraging a reduced polyoxomolybdate-alkoxide cluster for the formation of a stable U( <scp>v</scp> ) sandwich complex
Dominic Shiels, William W. Brennessel, Matthew R. Crawley, Ellen M. Matson
Abstract
], chemically or electrochemically, allows access to the U(v) centered species, which was characterized both spectroscopically and by single crystal X-ray diffraction. This represents the first example of a U(v)-polyoxometalate sandwich complex to be isolated and structurally characterized.
Topics & Concepts
PolyoxometalateAlkoxideCluster (spacecraft)ChemistryActinideRedoxInorganic chemistryCrystallographyStereochemistryCatalysisOrganic chemistryComputer scienceOperating systemPolyoxometalates: Synthesis and ApplicationsRadioactive element chemistry and processingVanadium and Halogenation Chemistry