Visible light-mediated radical fluoromethylation <i>via</i> halogen atom transfer activation of fluoroiodomethane
Patrick J. Deneny, Roopender Kumar, Matthew J. Gaunt
Abstract
Generation of fluoromethyl radicals via visible light-mediated halogen atom transfer activation of fluoroiodomethane facilitates both the multicomponent synthesis of α-fluoromethyl amines and the hydrofluoromethylation of electron-deficient alkenes.
Topics & Concepts
HalogenChemistryOrganic moleculesMoleculeAtom (system on chip)PhotochemistryCombinatorial chemistryGroup (periodic table)Organic chemistryComputer scienceAlkylEmbedded systemFluorine in Organic ChemistryRadical Photochemical ReactionsInorganic Fluorides and Related Compounds