Enzyme-mimicking of copper-sites in metal–organic frameworks for oxidative degradation of phenolic compounds
Ainara Valverde, Eneko Alkain, Natalia Ahiova Río-López, Luís Lezama, Arkaitz Fidalgo-Marijuán, José Manuel Laza, Stefan Wuttke, José Porro, Itziar Oyarzabal, Mónica Jiménez‐Ruiz, Victoria García Sakai, P.L. Arias, Iker Agirrezabal-Tellería, Roberto Fernández de Luis
Abstract
Two of the main factors controlling the activity and selectivity of metal sites within MOF-like copper metalloenzymes are: (i) their coordination environments, and (ii) the number and connectivity of metal ions at the active site ( i.e. , nuclearity).
Topics & Concepts
CopperChemistrySelectivityMetalDegradation (telecommunications)Metal-organic frameworkOxidative phosphorylationMetal ions in aqueous solutionInorganic chemistryCombinatorial chemistryOrganic chemistryCatalysisBiochemistryAdsorptionComputer scienceTelecommunicationsMetal-Organic Frameworks: Synthesis and ApplicationsMetal complexes synthesis and propertiesMetal-Catalyzed Oxygenation Mechanisms