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Studies on Dielectric, Super-Capacitive and Photoluminescence Properties of Metal Organic Frameworks Subjected to Varying Temperature and Frequencies

Gangadhar M. Kanaginahal, Rayappa Shrinivas Mahale, V. Shamanth, P.C. Sharath, Rajendrachari Shashanka

2023Nano hybrids and composites11 citationsDOIOpen Access PDF

Abstract

Metal organic frameworks when subjected to varying temperatures and frequencies. The analysis indicate the presence of guest molecules enhance the dielectric constant. The dielectric constant increase to a limit with the rise in temperature but it reduces gradually. The increase in frequencies enhance the peaks of permittivity towards higher temperatures. Shortening of ion diffusion also enhances the capacitance and a better contact between the electrode and active substance increases the electrochemical performance. Luminescence, the color depends on particle size, the structure and intermolecular packing of atoms in material. This paper gives an overview of MOFs studied based on their dielectric, super-capacitive and photo-luminescence when subjected to varying temperatures and frequencies.

Topics & Concepts

DielectricMaterials scienceCapacitive sensingLuminescenceCapacitanceIntermolecular forcePhotoluminescenceDiffusionPermittivityElectrodeOptoelectronicsMoleculeChemical physicsAnalytical Chemistry (journal)ChemistryThermodynamicsPhysical chemistryElectrical engineeringOrganic chemistryEngineeringPhysicsMetal-Organic Frameworks: Synthesis and ApplicationsGas Sensing Nanomaterials and SensorsConducting polymers and applications