Convenient access to π-conjugated 1,3-azaphospholes from alkynes via [3 + 2]-cycloaddition and reductive aromatization
Jannis Fidelius, Kai Schwedtmann, Sebastian Schellhammer, Jan Haberstroh, Stephen Schulz, Rongjuan Huang, Max Klotzsche, Antonio Bauzá, Antonio Frontera, Sebastian Reineke, Jan J. Weigand
Topics & Concepts
CycloadditionConjugated systemAromatizationSteric effectsCombinatorial chemistryCarbeneYield (engineering)ChemistryThermal stabilityScalabilityMaterials scienceOrganic chemistryComputer sciencePolymerCatalysisDatabaseMetallurgyN-Heterocyclic Carbenes in Organic and Inorganic ChemistrySulfur-Based Synthesis TechniquesOrganoboron and organosilicon chemistry