Litcius/Paper detail

Electrical current modulation in wood electrochemical transistor

Van Chinh Tran, Gabriella G. Mastantuoni, Marzieh Zabihipour, Lengwan Li, Lars A. Berglund, Magnus Berggren, Qi Zhou, Isak Engquist

2023Proceedings of the National Academy of Sciences19 citationsDOIOpen Access PDF

Abstract

The nature of mass transport in plants has recently inspired the development of low-cost and sustainable wood-based electronics. Herein, we report a wood electrochemical transistor (WECT) where all three electrodes are fully made of conductive wood (CW). The CW is prepared using a two-step strategy of wood delignification followed by wood amalgamation with a mixed electron-ion conducting polymer, poly(3,4-ethylenedioxythiophene)–polystyrene sulfonate (PEDOT:PSS). The modified wood has an electrical conductivity of up to 69 Sm −1 induced by the formation of PEDOT:PSS microstructures inside the wood 3D scaffold. CW is then used to fabricate the WECT, which is capable of modulating an electrical current in a porous and thick transistor channel (1 mm) with an on/off ratio of 50. The device shows a good response to gate voltage modulation and exhibits dynamic switching properties similar to those of an organic electrochemical transistor. This wood-based device and the proposed working principle demonstrate the possibility to incorporate active electronic functionality into the wood, suggesting different types of bio-based electronic devices.

Topics & Concepts

PEDOT:PSSMaterials scienceTransistorPolystyrene sulfonateCurrent collectorElectrodeElectrochemistryConductive polymerOptoelectronicsElectronicsPolymerNanotechnologyVoltageComposite materialElectrical engineeringChemistryElectrolyteEngineeringPhysical chemistryConducting polymers and applicationsAdvanced Sensor and Energy Harvesting MaterialsSupercapacitor Materials and Fabrication